Add onions and garlic to hot drippings in pot, and cook over mediumv, stirring often, until golden brown, about 25 minutes. Add ham hocks, and cook until browned on all sides, about 5 minutes, turning ham hocks every 45 seconds. Add bourbon and vinegar, and cook, stirring and scraping up browned bits on bottom of pot, until liquid is reduced by half, about 30 seconds. Add 8 cups cold water; bring to a simmer.
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